Studies on A Novel Mixed-Valence Complex of Copper(Ⅰ,Ⅱ)α-Methacrylate with Imidazole and Aqua  

作　　者：Yao Yu WANG Xin WANG Qian SHI Qi Zhen SHI Yi Ci GAO(Department of Chemistry, Northwest University, Xian, 710069)(Department of Chemistry, Lanzhou University, Lanzhou. 730000) 

出　　处：《Chinese Chemical Letters》1999年第2期187-188,共2页中国化学快报（英文版）

摘　　要：A novel mixed-valence copper (Ⅰ,Ⅱ) complex Cu3 [CH2=C(CH3) COO]5 (imH)3 (H2O)has been synthesized and characterized by XPS spectra and single crystal X-ray structural analysis.The title complex crystallized in monoclinic space group P21/c, with α=11 .225 (3), b=13.9023 (12),c=24.559 (2), β=92.372 (10)°and Z=4. Final R=0.0495 for 5546 reflections [I＞2σ (Ⅰ)].A novel mixed-valence copper (Ⅰ,Ⅱ) complex Cu3 [CH2=C(CH3) COO]5 (imH)3 (H2O)has been synthesized and characterized by XPS spectra and single crystal X-ray structural analysis.The title complex crystallized in monoclinic space group P21/c, with α=11 .225 (3), b=13.9023 (12),c=24.559 (2), β=92.372 (10)°and Z=4. Final R=0.0495 for 5546 reflections [I＞2σ (Ⅰ)].

关 键 词：Mixed-valence copper (Ⅰ Ⅱ) complex synthesis crystal structure 

分 类 号：O627[理学—有机化学]