Synergistic Effect in Mixed Capillary Gas Chromatographic Stationap Phases Containing Heptakis(2,3,6-tri-o-pentyl)-β-cyclodextrin and Dibenzo-18-crown-6  

作　　者：Li Ming YUAN Ruo Nong FU Xue Xian CHEN Shi Hong GUl Rong Ji DAI (Chemistry Department of Yunnan Normal University.Kunming 650092)(Department of Chemical Engineering.Beijing institute of Technology,BEijing 100081)(Solar Energy Research Institute ofyunna 

出　　处：《Chinese Chemical Letters》1999年第3期223-226,共4页中国化学快报（英文版）

摘　　要：used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well as comparing with the heptakis（2．3、6-tri-O-pentyl）-β-cyclodextrin and thedibenzo-18-crown-6 used as individual stationary phase、the synergistic effects were observed.These effects were affected by the column temperature．mixed ratio and linear velocity of carrier gas．used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well as comparing with the heptakis（2．3、6-tri-O-pentyl）-β-cyclodextrin and thedibenzo-18-crown-6 used as individual stationary phase、the synergistic effects were observed.These effects were affected by the column temperature．mixed ratio and linear velocity of carrier gas．

关 键 词：Gas chromatography mixed stationary  phase synergistic effect heptakis（2．3．6-tri-o-pentyl）-β-cyclodextrin DIBENZO-18-CROWN-6 

分 类 号：O625.1[理学—有机化学]