STUDIES ON THE ADDITION REACTION OF GRIGNARD REAGENTS TO α-CINNAMOYLKETENE(1,3-PROPYLENE)DITHIOACETALS  

STUDIES ON THE ADDITION REACTION OF GRIGNARD REAGENTS TO α-CINNAMOYL KETENE (1,3-PROPYLENE) DITHIOACETALS

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作  者:Qun Xing FANG Chun LIN Shu Jia ZHANG Qun LIU (Department of Chemistry , Northeast Normal University, Changchun, 130024) 

出  处:《Chinese Chemical Letters》1996年第1期5-6,共2页中国化学快报(英文版)

摘  要:The addition reaction of Grignard reagents to a-cinnamoyl ketene(l,3propylene) dithoacetals was performed . The experiments show that the addition proceeds completely in a conjugated l,4-manner. Possible mechanism for the reaction selectivity is discussed.The addition reaction of Grignard reagents to a-cinnamoyl ketene(l,3propylene) dithoacetals was performed . The experiments show that the addition proceeds completely in a conjugated l,4-manner. Possible mechanism for the reaction selectivity is discussed.

分 类 号:O621.25[理学—有机化学]

 

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