A NEW METHOD FOR PBEPARATION OF IBON(Ⅲ) PORPHYRIN OXYANION OMPLEXES -SYNTHESIS OF PERCHLORATE(PORPHYINATO) IRON(Ⅲ)  

作　　者：Xin Hua ZHONG Yao Yu FENG Jie Sheng HUANG and Pan Wen SHEN(Departemt ot Chemistry. Nankai University, Tianjin 300071)(Institute of Chemical Engineering,Tianjin University, Tianjin 300072) 

出　　处：《Chinese Chemical Letters》1996年第2期187-188,共2页中国化学快报（英文版）

摘　　要：A new method for preparetion of iron(III) porphyrin oxyanion complexes was reported. By this method perchiorate complex of iron(III) tetraphenylporphyrin [FeTPP(OClO3)] was prepared from i-butylamine complex of iron(II) porphyrin [Fe(TPP(NH2Bui)2 by treatment with perchloric acid.A new method for preparetion of iron(III) porphyrin oxyanion complexes was reported. By this method perchiorate complex of iron(III) tetraphenylporphyrin [FeTPP(OClO3)] was prepared from i-butylamine complex of iron(II) porphyrin [Fe(TPP(NH2Bui)2 by treatment with perchloric acid.

分 类 号：O6[理学—化学]