Carbonylation　of　Allyl　Chloride　Catalyzed　by　PdCl_2（TPPTS）_2　in　Two－phase　Medium  

作　　者：Jiang, H Xu, Y Liao, SJ Yu, DR Chen, H Li, XJ 

机构地区：[1]CHINESE ACAD SCI,DALIAN INST CHEM PHYS,DALIAN 116023,PEOPLES R CHINA [2]SICHUAN UNIV,DEPT CHEM,CHENGDU 610064,PEOPLES R CHINA

出　　处：《Chinese Chemical Letters》1996年第9期847-848,共2页中国化学快报（英文版）

摘　　要：PdCl2(TPPTS)2 exhibits very high catalytic activity for carbonylation of allyl chloride in aq. NaOH / toluene two-phase medium under atmospheric pressure.The average turnover frequency (TOFav,mol substrate / mol Pd·min) reaches 31 min(-1).PdCl2(TPPTS)2 exhibits very high catalytic activity for carbonylation of allyl chloride in aq. NaOH / toluene two-phase medium under atmospheric pressure.The average turnover frequency (TOFav,mol substrate / mol Pd·min) reaches 31 min(-1).

分 类 号：O643.32[理学—物理化学]