Studies on Functionally Substituted n5-Cyclopentadienyl Transition-Metal Compounds --Synthesis and Crystal Structure of η5-CH3COC5H4W(CO)3CH2C5H5  

作　　者：Song Licheng , Yang Hua and Hu Qingmei (Department of Chemistry, Nankai University, Tianjin)Zhou Zhongyuan (Chengdu Center of Analysis and. Determination, Academia Sinica, Chengdo) 

出　　处：《Chemical Research in Chinese Universities》1990年第1期14-19,共6页高等学校化学研究（英文版）

摘　　要：Reaction of benzyl chloride with η5-CH3COC5H4W(CO)2Na formed in situ from η6-CH3CO C6H4Na and W(CO)2 gives η6-CH3COC6H4W(CO)3CH2C5H5.The single crystal structure of the product was determined by X-ray diffraction method. It crystallizes in the triclinlc space group P1 with unit cell parameters a= 10.199(5),b=12.116(7), c=14.207(6)A;a=69.47(5),β=72. 38(3),γ= 85.89(4);V= 1569. 9A3, Dc= 1.98 g/cm2; Z=4. Least-square refinement led to final R value of 0. 0539 and Rw value of 0. 0553, based on 3548 independent observed reflections.Reaction of benzyl chloride with η5-CH3COC5H4W(CO)2Na formed in situ from η6-CH3CO C6H4Na and W(CO)2 gives η6-CH3COC6H4W(CO)3CH2C5H5.The single crystal structure of the product was determined by X-ray diffraction method. It crystallizes in the triclinlc space group P1 with unit cell parameters a= 10.199(5),b=12.116(7), c=14.207(6)A;a=69.47(5),β=72. 38(3),γ= 85.89(4);V= 1569. 9A3, Dc= 1.98 g/cm2; Z=4. Least-square refinement led to final R value of 0. 0539 and Rw value of 0. 0553, based on 3548 independent observed reflections.

关 键 词：η5-Acetylcyclopentadienyl 6-Benzyl tungsten compounds SYNTHESIS Crystal structure 

分 类 号：O6[理学—化学]