ESTERIFICATION ON ZEOLITES  

作　　者：陈子涛 仲君实 李齐芳 李研红 区兆华 

机构地区：[1]Department of Chemistry, Nanjing University

出　　处：《Science China Chemistry》1989年第7期769-775,共7页中国科学（化学英文版）

摘　　要：Primary, secondary, and tertiary alcohols and polyols were esterified with carboxylic acidin the presence of HY zeolite. Yield of ester of primary alcohol is over 80 per cent, andthat of sec- and tert-alcohols, 40-50 per cent generally.γ-Lactone was synthesized byrearrangement of α- or β-octylenic to tridecylenic acid with HY zeolite.Primary, secondary, and tertiary alcohols and polyols were esterified with carboxylic acidin the presence of HY zeolite. Yield of ester of primary alcohol is over 80 per cent, andthat of sec- and tert-alcohols, 40-50 per cent generally.γ-Lactone was synthesized byrearrangement of α- or β-octylenic to tridecylenic acid with HY zeolite.

关 键 词：direct ESTERIFICATION of ALCOHOLS ester of POLYOL Γ-LACTONE REARRANGEMENT of α/β-alkenyl acid 

分 类 号：O6[理学—化学]