THE SYNTHESES OF POLYQUINOLINES WITH 2,2'-PYRIDYLQUINOLINE AND 2,6-DIQUINOLYLPYRIDINE AS LIGAND AND THEIR APPLICATIONS IN SOME CATALYTIC REACTIONS  

作　　者：丁孟贤 TOHNK.STILLE 

机构地区：[1]Department of Chemistry,Colorado State University,Fort Collins,Colorado 80523 USA

出　　处：《Chinese Journal of Polymer Science》1989年第4期360-366,共7页高分子科学（英文版）

摘　　要：The polyquinolines with 2,2'-pyridylquinoline as bidentate and 2,6-diquinolylpyridine as tridentate ligand have been prepared from 4,4-dlamino- 3,3'-dibenzoyldiphenyl ether, 4,4'-diacetyldiphenyl ether and 1,4-bis (2-acetylpyridyl-6-oxy) benzene, 2,6-diacetylpyridine, respectively. These polyquinoline-supported ligands have been used in hydrogenation and hydroformylation of olefins with some transition metal complexes.The polyquinolines with 2,2'-pyridylquinoline as bidentate and 2,6-diquinolylpyridine as tridentate ligand have been prepared from 4,4-dlamino- 3,3'-dibenzoyldiphenyl ether, 4,4'-diacetyldiphenyl ether and 1,4-bis (2-acetylpyridyl-6-oxy) benzene, 2,6-diacetylpyridine, respectively. These polyquinoline-supported ligands have been used in hydrogenation and hydroformylation of olefins with some transition metal complexes.

关 键 词：PYRIDYLQUINOLINE AND 2 6-DIQUINOLYLPYRIDINE AS LIGAND AND THEIR APPLICATIONS IN SOME CATALYTIC REACTIONS THE SYNTHESES OF POLYQUINOLINES WITH 2 2 

分 类 号：O63[理学—高分子化学]