PHOTO-DISPROPORTIONATION OF μ-OXO-BIS-TETRA-4-TERT-AMYLPHENOXY-PHTHALOCYANINATO-IRON(Ⅲ) AND CATALYSIS OF OXYGEN TRANSFER REACTION  

作　　者：沈淑引 蔺恕群 寿涵森 虞群 许慧君 陈德文 

机构地区：[1]Institute of Photographic Chemistry, Academia Sinica, Beijing [2]Institute of Chemisty, Academia Sinica, Beijing

出　　处：《Chinese Science Bulletin》1989年第3期259-260,共2页

摘　　要：In 1982, A. B. P. Lever reported that μ-oxo-bis-phthalocyaninato iron （Ⅲ） （PcFe^Ⅲ）₂O photoreduced when irradiated under nitrogen, yielding PcFe（Ⅱ） and an oxoiron species. The mechanism of this photo-disproportionation remained in question. We have synthesized tetra-4-tert-amylphenoxy-phthalocyaninato-iron （Ⅱ）. It dissolves in benzene containing pyridine and absorbs oxygen in the air forming （PcFe^Ⅲ）₂O with absorption at 620 nm. Irradiation of a degassed solution of （PcFe^Ⅲ）₂·

关 键 词：TERT TETRA pyridine benzene TETRA irradiated YIELDING irradiation revers cleavage 

分 类 号：N[自然科学总论]