SOME ELECTRICALLY CONDUCTING 7,7,8,8-TETRACYANO-QUINODIMETHANE (TCNQ) LANTHANIDE SALTS  

作　　者：王序昆 田志刚 王者福 林沝 

机构地区：[1]Institute of Elementoorganic Chemistry,Nankai University,Tianjin [2]Central Laboratory,Nankai University,Tianjin

出　　处：《Chinese Science Bulletin》1989年第15期1274-1277,共4页

摘　　要：In research work, little has been heard of the lanthanide salts of TCNQ, preliminary reports were known of the synthesis of Ce³⁺（TCNQ）₃·6H₂O and Sm³⁺（TCNQ）₃·6H₂O and the electrical resistivity of the latter compound （2×10⁴ ohm·cm）. This note reports the synthesis of 11 TCNQ lanthanide salts and 5 TCNQ lanthanide salts with macrocyclic ligand and their spectroscopic and electrical properties.<正> In research work, little has been heard of the lanthanide salts of TCNQ, preliminary reports were known of the synthesis of Ce3+（TCNQ）3·6H2O and Sm3+（TCNQ）3·6H2O and the electrical resistivity of the latter compound （2×104ohm·cm）. This note reports the synthesis of 11 TCNQ lanthanide salts and 5 TCNQ lanthanide salts with macrocyclic ligand and their spectroscopic and electrical properties.

关 键 词：organic conduetor TCNQ salt LANTHANIDE 

分 类 号：N[自然科学总论]