环己烷甲酸根桥联的二维锰配合物的合成与表征(英文)  

Synthesis and Characterization of A Two-Dimensional Mn Complex Bridged by Cyclohexanecarboxylate

作　　者：王君[1,2] 马运声[2] 袁荣鑫[2] 谢吉民[1] 

机构地区：[1]江苏大学化学化工学院,江苏镇江212013 [2]常熟理工学院化学与材料工程系江苏省新型功能材料重点建设实验室,江苏常熟215500

出　　处：《无机化学学报》2009年第4期742-745,共4页Chinese Journal of Inorganic Chemistry

基　　金：江苏省自然科学基金(No.BK2006044);江苏省教育厅重大基金(No.06KJA43014)资助项目

摘　　要：Complex [Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4'-bipy in methanol.The title complex crystallizes in triclinic space group P1,with a=1.008 8(2) nm,b=1.086 3(1) nm,c=1.164 9(3) nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V= 1.125 4(4) nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4'-bipy into a 2D plane.CCDC:692247.Complex[Mn2（C6H11CO2）3（4,4＇-bipy）2（H2O）2]ClO4（C6H11CO2H=cyclohexanecarboxylic acid） was synthesized by reaction of Mn（ClO4）2·6H2O, C6H11CO2Na and 4,4＇-bipy in methanol. The title complex crystallizes in triclinic space group P^-1, with a=1.0088（2） nm, b=1.0863（1）nm, c= 1.1649（3）nm, α=63.016（3）°,β=81.998（4）°, γ=88.604（1）°, V= 1.1254（4）nm^3, Z=1. There are two types of Mn atoms in the structure with each in octahedral geometry. Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4＇- bipy into a 2D plane. CCDC： 692247.

关 键 词：合成 表征 锰 环己烷甲酸根 

分 类 号：O614.122[理学—无机化学]