卟啉在表面活性剂溶液中的聚集态  

The Aggregation Behaviours of the Porphyrins in Surfactant Solutions

作　　者：黄涛[1] 王永强[2] 田永驰 李伯符 梁映秋[3] 

机构地区：[1]武汉化工学院 [2]吉林大学理化所 [3]南京大学

出　　处：《武汉化工学院学报》1998年第1期1-4,共4页Journal of Wuhan Institute of Chemical Technology

基　　金：国家自然科学基金

摘　　要：利用紫外可见吸收光谱研究了具一个（Ｐ１）、两个（ｃｉｓＰ２和ｔｒａｎｓＰ２）、三个（Ｐ３）和四个（Ｐ４）十六烷氧基链的卟啉在十二烷基硫酸钠溶液中的聚集态，结果表明卟啉的存在状态受侧链的数目和相对位置所控制．据与Ｃｕ２＋络合反应速率进一步分析了卟啉在胶束中的相对位置，其中Ｐ４以Ｂ带劈裂聚集体稳定存在于胶束内，Ｐ１和ｔｒａｎｓＰ２被胶束增溶，卟啉环位于或接近于界面．Aggregation behaviours in SDS solution for P_4,P_3,cisP_2,transP_2 and P_1 were studied by UVVis absorption spectra. The results show that the aggregation behaviours would be controlled by the number of the long hydrocarbon chains on the macrocycle with different substitutive sites.The microenvironment were investigated by Cu^2+ incorporation into the porphyrins. With higher hydrophobicity,P_4 tends to form Bstate splitting aggregate in micella. P_1 and transP_2 can be solubilized and stabilized as monomer,the macrocycles are at or near the interface.

关 键 词：卟啉 聚集态 表面活性剂 溶液 

分 类 号：O626.13[理学—有机化学] O657.32[理学—化学]