可缩合聚合松香基高分子单体的研究进展  

Development of Polymerizable Rosin-Based Monomer Used for Step Polymerization

作　　者：王基夫[1] 林明涛[1,2] 王春鹏[1,2] 储富祥[1,2] 

机构地区：[1]中国林业科学研究院林产化学工业研究所 国家林业局林产化学工程重点开放性实验室,江苏南京210042 [2]中国林业科学研究院林业新技术研究所,北京100091

出　　处：《高分子材料科学与工程》2009年第4期170-174,共5页Polymer Materials Science & Engineering

基　　金：国家杰出青年科学基金(30325031);中央级公益性科研院所基本科研业务专项资金(CAFINT2007C12);林业公益性行业科研专项项目(200804011)

摘　　要：松香是一种重要的可再生资源,可用于合成高分子单体,其开发和应用近年来受到国内外广泛关注。文中主要从松香的Diels-Alder双烯加成反应和脱羧脱氢缩合反应两个方面,介绍可进行逐步聚合反应的松香基单体的合成和应用情况。Rosin is an important renewable resources, and attraces recently researcher＇s attention for its application as new polymerizable precursors in recent years. In this paper the polymerizable rosin-based monomers used for step polymerization were reviewed through the ways of Diels-Alder reaction and dehydrodecarboxylation reaction of rosin and its derivatives. The relevant application for polymer synthesis such as polyesters, polyamides, polyesterimides, polyamideimides and epoxy resins was also introduced. It demonstrates that rosin can be a potential resource for polymer synthesis.

关 键 词：逐步聚合 Diels-Alder双烯加成 脱羧脱氢缩合 松香基单体 

分 类 号：TQ314.22[化学工程—高聚物工业]