Crystal Structure of a Cu(Ⅱ) Coordination Polymer: [Cu(IP)(TBZH)]_(2n) (TBZH = Thiabendazole, IP = Isophthalic Acid)  

作　　者：王家军 吕明 孙亚明 崔运成 黄艳菊 李传碧 高广刚 

机构地区：[1]Chemistry Department of Jilin Normal University [2]Physics Department of Jilin Normal University

出　　处：《Chinese Journal of Structural Chemistry》2009年第4期434-438,共5页结构化学（英文）

基　　金：supported by Siping Sci-tech Development Planning Project (No. 2005012)

摘　　要：The structure of a copper（Ⅱ） polymer, [Cu（IP）（TBZH）]2n 1 （TBZH = thiabendazole, IP = isophthalic acid）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08A^°, β = 104.80°, V= 1666.0（3）A^°^3, Z = 4, Mr= 428.90, Dc= 1.710 g/cm^3, F（000） = 868,μ = 1.468 mm^-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.The structure of a copper（Ⅱ） polymer, [Cu（IP）（TBZH）]2n 1 （TBZH = thiabendazole, IP = isophthalic acid）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08A^°, β = 104.80°, V= 1666.0（3）A^°^3, Z = 4, Mr= 428.90, Dc= 1.710 g/cm^3, F（000） = 868,μ = 1.468 mm^-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.

关 键 词：THIABENDAZOLE copper（Ⅱ） complex single-crystal structure 

分 类 号：O631.3[理学—高分子化学]