β-Cyclodextrin promoted oxidation of aldehydes to carboxylic acids in water  

作　　者：Dong Po Shi Hong Bing Ji 

机构地区：[1]College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434023, China [2]School of Chemistry and Chemical Engineering of Sun Yat-Sen University, Guangzhou 510275, China

出　　处：《Chinese Chemical Letters》2009年第2期139-142,共4页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(No.20776053);the Program for New Century Excellent Talents in University(No.NCET-06-740)for providing financial support for this project.

摘　　要：A facile, efficient and substrate-selective oxidation of aldehydes to carboxylic acids with NaClO catalyzed by β-cyclodextrin in water has been developed. A series of aldehydes which could form inclusion complex with β-cyclodextrin （β-CD） were oxidized selectively with excellent yields.A facile, efficient and substrate-selective oxidation of aldehydes to carboxylic acids with NaClO catalyzed by β-cyclodextrin in water has been developed. A series of aldehydes which could form inclusion complex with β-cyclodextrin （β-CD） were oxidized selectively with excellent yields.

关 键 词：Substrate-selective OXIDATION β-Cyclodextrin （β-CD） ALDEHYDES 

分 类 号：O643.36[理学—物理化学] O636.12[理学—化学]