采用二元模板剂合成MCM-22分子筛的研究  

Study on synthesis of zeolite MCM-22 by adopting binary template

作　　者：吴雪红[1] 李懿桐[1] 蒋晶洁[1] 魏树权[1] 

机构地区：[1]哈尔滨师范大学化学化工学院,黑龙江哈尔滨150025

出　　处：《化学工程师》2009年第4期18-19,共2页Chemical Engineer

基　　金：黑龙江省教育厅基金资助项目(11531244);哈尔滨师范大学基金资助项目(KM2006-02)

摘　　要：以硅溶胶和偏铝酸钠分别为硅源和铝源制备MCM-22,采用动态水热法合成MCM-22分子筛,考察了以六亚甲基亚胺和哌嗪二元模板剂对合成MCM-22分子筛的影响。XRD和SEM分析表明:采用二元模板剂能够合成较纯的MCM-22分子筛,并且表面形貌基本相同。The zeolite MCM-22 synthesis was carried out using hexamethyleneimine （HMI） and piperazine （PIP） binary amines as templates under rotating conditions at 423K. The results showcd that the MCM-22 had been synthesized as a unique phase and with good crystallinities in a range of different HMI/PIP, 73% crystallinity of MCM-22 was obtained even at a low HMI/PIP molar ratio of 0.10/0.25. However, PIP was an effective template to direct the formation of ZSM-5 crytals when it was used alone.

关 键 词：MCM-22分子筛 哌嗪 六亚甲基亚胺 二元模板剂 

分 类 号：TQ424.25[化学工程]