甲烷自热重整制合成气热力学平衡分析  

Thermodynamics Equilibrium Analysis for Syngas Production by Methane Autothermal Reforming

作　　者：张舒冬[1] 金英杰[2] 倪向前[1] 张喜文[1] 孙万付[1] 方向晨[1] 

机构地区：[1]中石化抚顺石油化工研究院,辽宁抚顺113001 [2]辽宁石油化工大学,辽宁抚顺113001

出　　处：《当代化工》2009年第2期165-168,190,共5页Contemporary Chemical Industry

摘　　要：使用1stOpt2.5计算软件编程计算甲烷自热重整制合成气反应平衡组成,考察温度、原料比对体系组分平衡的影响。通过计算结果指出最适宜的反应条件,为甲烷自热重整制合成气催化剂的研究与开发提供热力学依据。Thermodynamics equilibrium analysis was performed on methane autothermal reforming to product syngas by 1 stOpt （version： 2.5 ）calculation software. The effects of temperature and molar ratio of feed on equilibrium conversion of methane and selectivity of carbon monoxide were studied. The optimization operation parameters were gained by calculation,which can provide thermodynamics basis for research and exploiture of catalyst of methane autothermal reforming to product syngas.

关 键 词：甲烷 自热重整 合成气 热力学平衡 

分 类 号：TQ221.11[化学工程—有机化工]