CaO-B_2O_3-SiO_2系玻璃形成区及性能研究  

Study on glass-forming regions and performance of CaO-SiO_2-B_2O_3 system

作　　者：许贵军[1] 周洪庆[1] 朱海奎[1] 陈栋[1] 刘敏[1] 

机构地区：[1]南京工业大学材料科学与工程学院,江苏南京210009

出　　处：《电子元件与材料》2009年第5期47-49,共3页Electronic Components And Materials

基　　金：国家“863”计划资助项目(No.2007AA03Z455)

摘　　要：采用XRD、SEM等手段,系统研究了CaO-B2O3-SiO2(CBS)系的玻璃形成范围,利用热分析结果计算了玻璃的析晶参数β。结果表明:纯CBS玻璃形成范围是x(B2O3)为10%～75%,x(SiO2)为0～45%,x(CaO)为25%～55%;整个玻璃形成区比较窄,并向B2O3方向伸展。添加x(Al2O3)为10%可以改善玻璃的失透,提高玻璃体的形成能力,使烧结后εr变化不大,由6.43变为6.31,tanδ显著增加,由0.0009增至0.0020。试样的主要晶相为CaB2O4、α-石英和CaSiO3。The glass-forming regions of CaO-B2O3-SiO2 system were studied by XRD, SEM etc methods and the devitrifying parameter β was calculated by thermal analysis results. The results show that the glass-forming regions are x（B2O3） from 10% to 75%, x（SiO2） from 0 to 45%, x（CaO） from 25% to 55%, the whole region is rather narrow and elongating to B203 direction. Adding mole fraction of 10% A1203 in the glass can improve the transparency and enhance the bulk glass forming ability, and εrchanges little, from 6.43 to 6.31, tanδ enhances remarkably from 0.000 9 to 0.002 0 after sintering. The major crystal phases of samples are CaB2O4, α-quartz and CaSiO3.

关 键 词：无机非金属材料 CaO—B2O3-SiO2玻璃 玻璃形成区 介电性能 

分 类 号：TM28[一般工业技术—材料科学与工程]