双(1′-苯基-3′-甲基-5′-氧代吡唑-4′-基)乙二酮萃取镧系元素  

Extraction of lanthanide ions with Bis(1phenyl3methyl5pyrazolone4yl) ethanedione

作　　者：韩维和[1,2] 高改玲[1,2] 梁宏斌[1,2] 韩丽[1,2] 钱博 

机构地区：[1]陕西师范大学化学系 [2]河南省商丘师范学校

出　　处：《陕西师大学报（自然科学版）》1998年第2期115-116,共2页Journal of Shaanxi Normal University(Natural Science Edition)

摘　　要：双（１′－苯基－３′－甲基－５′－氧代吡唑－４′－基）乙二酮萃取镧系元素韩维和１高改玲１梁宏斌１韩丽２钱博１（１陕西师范大学化学系，西安７１００６２；２河南省商丘师范学校，商丘４７６０００；第一作者，男，４６岁，副教授）４－酰代双吡唑酮是一类优良的螯...The extraction of Ln3+ (Ln=La,Pr,Nd,Gd) from nitric acid solutions with bis (1phenyl3methyl5pyrazolone4yl) ethanedione (H2BPMPED or H2A) has been studied. The composition of extracted compounds of Lathanide is shown to be Ln BPMPED·HBPMPED by the methods of slop and equimolar series. The pH values of half of extraction and thermodynamic function of extracted reaction have been determined.

关 键 词：镧系元素 萃取 乙二酮 

分 类 号：O614.33[理学—无机化学] O658.2[理学—化学]