Fluorescence and sensitization performance of phenylene-vinylene-substituted polythiophene  

作　　者：CHEN JinMao HOU JianHui LI YongFang ZHOU XiaoWen ZHANG JingBo LI XuePing XIAO XuRui LIN Yuan 

机构地区：[1]Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China [2]Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China [3]Graduate University of Chinese Academy of Sciences, Beijing 100190, China

出　　处：《Chinese Science Bulletin》2009年第10期1669-1676,共8页

基　　金：Supported by the Major State Basic Research Development Program of China (Grant No. 2006CB202605);High-Tech Research and Development of China Program (Grant No. 2007AA05Z439);National Natural Science Foundation of China (Grant No. 50221201);Innovative Foundation of the Center for Molecular Science, Chinese Academy of Sciences (Grant No. CMS-CX200718)

摘　　要：A new kind of polythiophene derivative, Poly(3-{2-[4-(2-ethylhexyloxy)-phenyl]-vinyl}-2,2′-bithiophene) (PTh), was applied in dye-sensitized solar cell to extend the light response of nanocrystalline TiO2 electrode. UV-vis absorption and fluorescence spectra were employed to investigate the interaction of PTh with nanocrystalline TiO2. The absorption coefficient of the PTh was high in visible part of spec- trum, and the fluorescence emission of the PTh can be efficiently quenched by TiO2 nanoparticles ow- ing to charge injection from the excited singlet state of PTh to the conduction band of the TiO2 particles. Cyclic voltammetry measurements were performed to study the dye regeneration reaction at the na- nocrystalline TiO2/electrolyte interface. The solar cell sensitized with PTh exhibited a short-circuit photocurrent (Isc) of 3.08 mA/cm2, an open circuit voltage (Voc) of 511 mV and an overall efficiency of 0.9% under the illumination of 100 mW/cm2 (AM 1.5).A new kind of polythiophene derivative, Poly（3-{2-[4-（2-ethylhexyloxy）-phenyl]-vinyl}-2,2＇-bithiophene） （PTh）, was applied in dye-sensitized solar cell to extend the light response of nanocrystalline TiO2 electrode. UV-vis absorption and fluorescence spectra were employed to investigate the interaction of PTh with nanocrystalline TiO2. The absorption coefficient of the PTh was high in visible part of spectrum, and the fluorescence emission of the PTh can be efficiently quenched by TiO2 nanoparticles owing to charge injection from the excited singlet state of PTh to the conduction band of the TiO2 particles. Cyclic voltammetry measurements were performed to study the dye regeneration reaction at the na- nocrystalline TiO2/electrolyte interface. The solar cell sensitized with PTh exhibited a short-circuit photocurrent （Isc） of 3.08 mA/cm^2, an open circuit voltage （Voc） of 511 mV and an overall efficiency of 0.9% under the illumination of 100 mW/cm^2 （AM 1.5）.

关 键 词：荧光光谱 取代聚噻吩 染料敏化太阳能电池 苯乙炔基 纳米TiO2电极 TIO2纳米粒子 性能 聚噻吩衍生物 

分 类 号：O614.33[理学—无机化学] TQ324.8[理学—化学]