C_(60)/C_(70)键联1,4-二-(咔唑-9-亚甲基)苯的电化学行为与双光子吸收  

Electrochemistry Behavior and Two-photon Absorption Characteristic of C_(60)/C_(70) Bonded with 1,4-Bis[(carbazole-9-yl)methyl]benzene

作　　者：谭海荣[1] 曾和平[1] 

机构地区：[1]华南理工大学化学与化工学院功能分子研究所,广州510641

出　　处：《高等学校化学学报》2009年第5期934-937,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20671036);广东省科技项目(批准号:2007B010500008;2008B01080030)资助

摘　　要：设计合成了C60键联1,4-二-(咔唑-9-亚甲基)苯(5)和C70键联1,4-二-(咔唑-9-亚甲基)苯(6),用红外、核磁共振和MALDI-TOF质谱进行了表征,确认了化合物5和6的结构,用循环伏安法研究了化合物5和6的电化学性质,并用Z扫描对其双光子吸收性质进行了研究.C60/C70 bonded with 1,4-bis [ （carbazole-9-yl）methyl ] benzene was synthesized and characterized by FTIR, ^1H NMR and MALDI-TOF. Electrochemical properties of compounds 5 and 6 were studied by cyclic vohammetry. In the meanwhile, two-photon absorption cross-sector values （ σTPA） of derivatives were also tested by open aperture Z scan experiment.

关 键 词：C60/C70 键联1 4-二-(咔唑-9-亚甲基)苯 循环伏安 双光子吸收 

分 类 号：O626.24[理学—有机化学]