多面体低聚倍半硅氧烷改性聚合物材料研究进展  

Progress in Polymer Materials Modified by Polyhedral Oligomeric Silsesquioxanes

作　　者：林谦[1] 陈超[1] 孙争光[1] 黄世强[1] 

机构地区：[1]湖北大学材料科学与工程学院,武汉430062

出　　处：《有机硅材料》2009年第3期194-198,共5页Silicone Material

基　　金：湖北省教育厅优秀中青年人才项目(Q20081004)

摘　　要：介绍了多面体低聚倍半硅氧烷(POSS)的特性及POSS的3种基本制备方法,综述了POSS改性聚合物的最新研究进展(包括POSS改性聚烯烃、聚丙烯酸酯、聚酰亚胺、环氧树脂等)及POSS改性聚合物作为阻燃材料、耐热材料、光电材料、膜材料等的应用,指出了POSS材料的研究与应用前景。The characteristics of POSS and the three kinds of basic synthesis methods for POSS monomers were introduced. The recent progress of polymer materials （ such as polyolefins, polyacrylates, polyimides, epoxy resins, ere） modified by POSS were reviewed. Meanwhile the applications of POSS modified polymer materials used as flame-retardant materials, heat-resistant materials, optoelectronic materials, and membrane materials and so on were summarized. The development trend of POSS - based hybrid materials was also pointed out.

关 键 词：多面体低聚倍半硅氧烷 杂化材料 POSS改性聚合物 三官能团硅烷 

分 类 号：O634.41[理学—高分子化学]