光致变色化合物螺萘并噁嗪的合成及光谱性能研究  

Study on synthesis and spectrum properties of photochromic spironaphthoxazine

作　　者：王成[1] 刘姝[1] 孔会民[1] 杨志范[1] 王川[1] 

机构地区：[1]长春工业大学化学工程学院,吉林长春130012

出　　处：《长春工业大学学报》2009年第2期133-136,共4页Journal of Changchun University of Technology

基　　金：吉林省科技厅应用基础理论研究资助项目(吉科合字第20010513号)

摘　　要：合成了一种含萘并螺噁嗪的光致变色化合物N-乙基-3,3-二甲基-5-甲氧基螺吲哚啉-2,3-’[3H]萘并[2,1-b][1,4]噁嗪。通过1HNMR,IR和元素分析表征了它的分子结构,利用紫外光谱和荧光光谱初步探索了目标产物的光致变色性能。吸收光谱结果表明,目标分子的氯仿溶液经紫外光照射后,其开环体在587 nm处有较强的吸收而呈现蓝色,停止紫外光照射,溶液恢复为无色,显示了良好的光致变色性能;发光光谱结果显示,目标分子经紫外光激发后其开环体在435 nm处有较强的蓝光发射。A compound, called as N-ethyl-3,3-dimethyl-5-methoxy -spiroindoline-2,3 ＇-[3H]-naphtho [2,1-b] [-1,4]oxazine, is synthesized which contains naphthalene ring. The chemical structure is characterized with ^1HNMR, IR and elementary analysis, and the photochromic properties are studied with UV and fluorescence spectrometers. The absorption spectrum experimental results indicated that the compound in trichloromethane solution has an intensive absorption at 587 nm and gave a blue color after UV radiation but back to the colorless when no radiation, which shows the good photochromic property. The fluorescence spectrum experimental results indicate that the compound display an intensive blue emission light at 435 nm.

关 键 词：光致变色 螺吲哚啉萘并噁嗪 光谱性能 

分 类 号：O621.3[理学—有机化学]