硫酸盐还原菌对18-8不锈钢点蚀行为的影响  

EFFECT OF SULFATE-REDUCING BACTERIA ON THE PITTING CORROSION BEHAVIOR OF 18-8 STAINLESS STEEL

作　　者：李付绍[1] 安茂忠[1] 刘光洲[2] 段东霞[2] 

机构地区：[1]哈尔滨工业大学化工学院,哈尔滨150001 [2]海洋腐蚀与防护国防科技重点实验室,青岛266071

出　　处：《金属学报》2009年第5期536-540,共5页Acta Metallurgica Sinica

基　　金：青岛市科技局资助项目YK010403~~

摘　　要：利用原子力显微镜(AFM)和电化学方法研究了海水中硫酸盐还原菌(SRB)对18-8不锈钢(18-8SS)点蚀过程的影响.AFM探测显示,微观蚀孔的生长速率在含SRB介质中明显高于在灭菌介质中.阳极循环极化结果表明,SRB的代谢产物显著降低了18-8SS的点蚀电位和再钝化电位;而且在含SRB介质中,18-8SS在短时间内就能被活化,表明SRB的代谢活动极大地促进了钝化层的破坏过程.阴极极化曲线表明,含SRB介质中单质硫或多态硫的还原是促使点蚀生长的主要因素,其阴极还原电流密度可以达到很高的数值(>10μA/cm^2).Pitting corrosion of stainless steels is a very complex process in the chloride containing media with sulfate reducing bacteria （SRB）. Sulfate reduction by SRB results in the production of sulfur containing species, which can significantly change the media state and ultimately affect both the pit-initiation （breakdown of passive film） and the pit growth. In the present study, the effect of SRB on the pitting corrosion behavior of 18-8 stainless steel （18-8SS） in seawater was investigated by atomic force microscopy （AFM） and electrochemical methods. As the resultsshow, 18-8SS can be quickly activated in the media with SRB, indicating that bacterial activities can accelerate greatly the process of breakdown of passive film; Measurements with AFM probe demonstrate that the rate of micropit growth of 18-8SS in the media with SRB is conspicuously higher than that in the sterilized media. As for the pitting corrosion mechanism, bacterial metabolites make the pit potential （Epit） and the repassivation potential （Erep） both decrease distinctly; However, Epit of 18-8SS is still more positive than the redox potential （Eh） of the media state, Erep of 18-8SS more positive than the reversible hydrogen electrode potential, and thus it is proposed that the localized free oxygen resulting from sulfidation of passive film in the media with SRB is the main factor which causes the breakdown of passive film; Subsequently, sulfur element or polysulfide in the media with SRB is the main factor which sustains the pit-growth, and the current density for cathodic reduction of sulfur element or polysulfide can reach to a very high level （〉10 μA/cm^2）.

关 键 词：硫酸盐还原菌 点蚀 原子力显微镜 阳极循环极化 XPS分析 

分 类 号：TG174.3[金属学及工艺—金属表面处理]