C60与N-羧甲基脱氢枞胺的1,3-偶极环加成反应研究  

Study on 1,3-Dipolar Cycloaddition of C_(60) with N-Carboxymethyl Dehydroabietylamine

作　　者：熊垚[1] 林中祥[1] 范旭[1] 邓慧敏[2] 

机构地区：[1]南京林业大学化学工程学院,南京210037 [2]中山大学分析测试中心,广州510275

出　　处：《化学通报》2009年第5期474-477,共4页Chemistry

基　　金：国家自然科学基金项目(30371139,30871989)资助

摘　　要：以脱氢枞胺的衍生物N-羧甲基脱氢枞胺与C60及多聚甲醛为原料,于N2保护下在甲苯中回流48h,经1,3-偶极环加成反应,得到脱氢枞胺基团加成度不同的三种C60吡咯烷衍生物,并对它们的结构进行了表征。Three C60 pyrrolidine derivatives with different addition degrees of dehydroabietylamine groups were synthesized through the 1,3-dipolar cycloaddition of N-carboxymethyl dehydroabietylamine with C60 and formaldehyde in toluene for refluxing 48 hours in the atmosphere of nitrogen, and their structures were characterized.

关 键 词：C60脱氢枞胺 1 3-偶极环加成 吡咯烷衍生物 

分 类 号：O621.25[理学—有机化学]