四氮杂杯[2]芳烃[2]三嗪叠氮化衍生物的合成及其与RDX的配合研究  

Studies on synthesis of tetraazacalix[2]arene[2]triazine azides-derivative and it's derivation complex with RDX

作　　者：王晶[1] 曹端林[1] 胡志勇[1] 张文艳[1] 

机构地区：[1]中北大学化工与环境学院,山西太原030051

出　　处：《天津化工》2009年第3期16-18,共3页Tianjin Chemical Industry

摘　　要：本文合成了氮原子桥连杯[2]芳烃[2]三嗪化合物。室温下,以碳酸钾为缚酸剂,利用三聚氯氰和间苯二胺的亲核取代反应合成主体,并将其叠氮化,反应温度为40℃。产物通过元素分析,红外光谱和氢谱对其结构进行了表征,并采用XRD对氮杂杯[4]芳烃及其衍生物与黑索今的配合性能进行了表征分析,结果表明主客体之间发生了相互作用。We synthesized Aza-bridged calix[2]arene[2]triazines.At room temperature,Tetraazacalix[2]arene[2] triazine have been synthesized by m-phenylenediamine and cyanuric chloride,and potassium carbonate was taken as neutralisatal reagents.h was a nucleophillic substitution reaction.Then,it＇s azides was synthesized by sodium and Tetraazacalix [2]arene [2]triazine,at 40℃.The product was characterized by melting point,IR,element analysis and HNMR,we also investigated the complex by XRD.The experiment results showed that there was reciprocity between host and guest.

关 键 词：超分子化学 杂原子杯芳烃 三聚氯氰 合成 

分 类 号：TQ031.2[化学工程]