3-芳基-5-巯基-1,2,4-三唑衍生物的亲核反应研究  

Study on Nuleophilic Reaction of 3-Aryl-5-mercapto-1,2,4-triazoles

作　　者：张正强[1] 吴奇[1] 王德忠[1] 王凯[1] 史海健[1] 

机构地区：[1]南京工业大学化学化工学院,江苏南京210009

出　　处：《合成化学》2009年第3期272-278,共7页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(200771059);江苏省高校自然科学基金资助项目(05KJB-150039)

摘　　要：研究了碱性条件下3-芳基-5-巯基-1,2,4-三唑与丙烯腈或丙烯酸甲酯的亲核反应,得到31个新的3-芳基-1,2,4-三唑-5-硫酮类衍生物,其结构经NMR,IR,MS和元素分析表征。Nuleophilic reactions of 3-aryl-5-mereapto-1,2,4-triazoles with aerylonitrile or methyl acrylate were investigated in the presence of base to obtain thirty one novel 3-aryl-1,2,4- triazole-5-thione derivatives. The structures were characterized by NMR, IR, MS and elemental analysis.

关 键 词：三唑 丙烯腈 丙烯酸甲酯 硫酮 亲核反应 

分 类 号：O626.26[理学—有机化学]