杂萘联苯聚醚砜及其磺化物溶解度参数  

Solubility parameters of poly(phthalazinone ether sulfone) and sulfonated poly(phthalazinone ether sulfone)

作　　者：蹇锡高[1] 王珺[1,2] 张守海[1] 杨大令[1] 

机构地区：[1]大连理工大学化工学院,辽宁大连116012 [2]山西太钢不锈钢股份有限公司技术中心,山西太原030003

出　　处：《大连理工大学学报》2009年第3期322-326,共5页Journal of Dalian University of Technology

摘　　要：用基团贡献法通过拆分计算出"=N-"的基团贡献数据Fdi、Fpi、Ehi值,并对杂萘联苯聚醚砜及磺化杂萘联苯聚醚砜的三维溶解度参数进行计算,得出了不同磺化度磺化杂萘联苯聚醚砜三维溶解度参数各分量δd、δp和δh的计算公式.结果表明,随着磺化度的提高,磺化杂萘联苯聚醚砜的三维溶解度参数中δh分量显著提高,δp分量略有增加,而dδ分量变化不明显,磺化聚合物的溶解区域向高hδ方向移动.计算结果与实验结果吻合较好,对以后实验中溶剂的选择有重要的指导意义.The group contribution factors Fdi, Fpi and Ehi of ＂ -N- ＂ were calculated by group contribution method. The three-dimension solubility parameters of poly （phthalazinone ether sulfone） （PPES） and sulfonated poly （phthalazinone ether sulfone） （SPPES） were calculated, and the mathematic formulations of solubility parameters components δd, δp and δh at different sulfonation degrees were also suggested. The results indicate that as the sulfonation degree increases, the hydro-component （δh） of SPPES three-dimension solubility parameters increases obviously, the polar component （δp） increases smoothly, and the change of dispersive component （δd） can be neglected, the solubility area of SPPES moves toward high hydro-component （δh） area. The calculation results are in good accordance with the experimental ones, and these results are important for the solvents selection of SPPES in future experiments.

关 键 词：杂萘联苯 聚醚砜 基团贡献法 溶解度参数 磺化 

分 类 号：O631[理学—高分子化学]