水热合成法制备{[Cu(en)_(2)][KFe(CN)_(6)]}_(n)  

Hydrothermal Synthesis Method it Products[Cu(en)_(2)][KFe(CN)_(6)]}_(n)

作　　者：阿力塔[1] 徐秀廷[1] 刘淑琴[1] 梁娜[1] Alita;XU Xiu—ting;LIU Shu—qin;LIANG Na(College of Chemistry,Inner Mongolia University for Nationalities,Tongliao 028043,China)

机构地区：[1]内蒙古民族大学化学学院,内蒙古通辽028043

出　　处：《内蒙古民族大学学报(自然科学版)》2009年第3期275-277,共3页Journal of Inner Mongolia Minzu University:Natural Sciences

摘　　要：{[Cu(en)_(2)][KFe(CN)_(6)]}_(n)可通过配阳离子[Cu(en)_(2)]^(2+)和配阴离子[KFe(CN)_(6)]^(2-)自我组装而成.这是一种既有磁性又能导电的聚合物,因此可作为磁性材料、化学电源、电子器件、特殊涂层、传感器和电催化作用.本实验利用水热合成的方法制备一个铜配合物{[Cu(en)_(2)][KFe(CN)_(6)]}_(n),通过红外光谱和紫外光谱对其进行表征,研究了该化合物的溶解性,并讨论了配阳离子和配阴离子的配比对{[Cu(en)_(2)][KFe(CN)_(6)]}_(n)形成的影响.The complex{[Cu(en)_(2)][KFe(CN)_(6)]}_(n) can be passed to go together with coordination cation[Cu(en)_(2)]^(2+)and coordination anion[KFe(CN)_(6)]^(2-)by free linking.The complex is a kind of material with functions of magnetism and conducting electricity,therefore be a magnetic material,supplying chemistry power,electronics spare part,special layer and the electricity catalyst function.Using the hydrothermal synthesis method it products one complex{[Cu(en)_(2)][KFe(CN)_(6)]}_(n),and we can do crystal characterization through the infrared spectrum and ultraviolet spectrum.We can research the solubility products and discuss the ratio of influence between coordination cation and coordination anion for{[Cu(en)_(2)][KFe(CN)_(6)]}_(n).

关 键 词：水热合成 {[Cu(en)_(2)][KFe(CN)_(6)}_(n) 红外 紫外 

分 类 号：O611.4[理学—无机化学]