稀土N-苯基邻氨基苯甲酸-1,10-邻菲咯啉二元、三元配合物的合成、表征及其光物理性质  

The Synthesis, Characterization and Photophysical Properties of Binary and Ternary Rare Earth Complexes with N Phenylanthranilic Acid and 1,10 Phenanthroline

作　　者：阎冰[1] 张洪杰[1] 王淑彬[1] 倪嘉缵[1] 

机构地区：[1]中国科学院长春应用化学研究所稀土化学与物理开放实验室

出　　处：《高等学校化学学报》1998年第5期671-675,共5页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金;中科院院长基金

摘　　要：合成了几种新型的稀土（钆，铕，铽）的Ｎ－苯基邻氨基苯甲酸－１，１０－邻菲咯啉的二元、三元配合物．以元素分析、红外光谱和紫外光谱进行了表征，确定了组成．同时以低温磷光光谱确定了配体的三重态能级为２４３３０ｃｍ－１，研究了配体与稀土离子的能级匹配．详细讨论了配合物的光物理性质如发光性能和配体与稀土离子之间以及有机配体之间的分子内能量传递机制，结果发现，铽的Ｎ－苯基邻氨基苯甲酸－１，１０－邻菲咯啉配合物的发光性能良好．Some novel binary and ternary complexes of rare earth(Gd, Eu ,Tb) with N Phenylanthranilic acid and 1,10 Phenanthroline were synthesized by homogenous precipitation and their compositions were characterized by elemental analysis, IR spectra and UV Vis spectra. The triplet state energies of N Phenylanthranilic acid was determined to be 24 330 cm -1 with the phosphorescence spectra of its gadolinium complexes and the energy match between the ligand and the central rare earth ions was studied. The photophysical properties such as luminescence properties and intramolecular energy transfer match between rare earth ions and ligands and between ligands were discussed. The result indicates that terbium complexes with N Phenylanthranilic acid and 1,10 Phenanthroline have excellent luminescence properties.

关 键 词：稀土 配合物 邻菲咯啉衍生物 钆 铕 铽 发光材料 

分 类 号：O614.33[理学—无机化学]