C_(60)(OH)_n的快速制备及其机理研究  

Studies on the Rapid Preparation of Fullerols and Its Formation Mechanism

作　　者：李添宝[1,2] 黄克雄[1,2] 李新海[1,2] 蒋汉瀛[1,2] 李晶 颜星中[1,2] 黎军[1,2] 赵善楷[1,2] 

机构地区：[1]中南工业大学冶金物理化学及化学新材料研究所 [2]中山大学分析测试中心

出　　处：《高等学校化学学报》1998年第6期858-860,共3页Chemical Journal of Chinese Universities

基　　金：中国有色金属工业总公司高技术新材料项目资助

摘　　要：Ｃ６０（ＯＨ）ｎ在生物、医药、高分子材料等许多方面具有应用前景［１～３］，其合成对Ｃ６０衍生物的水溶液化学研究与合成新的有机化合物具有重要意义．利用各种不同的方法合成出羟基个数各不相同的Ｃ６０（ＯＨ）ｎ（ｎ＝１０～２６）已有报道［４～８］，但这些方法...In this paper, we introduce a very rapid preparation method to produce water soluble C 60 derivativesfullerols by the reaction of C 60 with aqueous NaOH and H 2O 2 in the presence of tetrabutylammonium hydroxide(TBAH) as the catalyst, and the reaction is accelerated very much and the reaction time is shortened from 1￣3 d to 1￣3 h by adding H 2O 2 to replace O 2 in the air as the oxidant. FTIR, 1H NMR and MALDI TOF MS proved the multi hydroxy and C 60 cage structure of the products. The hydroxylated fullerere epoxidethe intermediate which is very easy to hydrolyze to become fullerols was obtained, and the formation mechanism of fulleols was put forward.

关 键 词：富勒醇 制备 羟基化 富勒烯环氧化物 C60衍生物 

分 类 号：O613.71[理学—无机化学] O635.1[理学—化学]