八丁氧基萘酞菁钴(Ⅱ)的合成、表征和性质  

SYNTHESIS, CHARACTERIZATION AND PROPERTIESOF THE OCTABUTOXY 2,3NAPHTHALOCYANINE COBALT(Ⅱ)

作　　者：左霞[1] 吴谊群[1] 段武彪[1] 毛桂杰 邵延文 杨素玲 刘尔生[2] 陈耐生[2] 黄金陵[2] 

机构地区：[1]黑龙江大学化学系 [2]福州大学化学系

出　　处：《无机化学学报》1998年第2期226-229,共4页Chinese Journal of Inorganic Chemistry

基　　金：黑龙江自然科学基金

摘　　要：采用１，４－二丁氧基２，３－二氰基萘和无水氯化钴在１，８－二氮杂双环［５．４．０］十一－７烯（ＤＢＵ）存在下，醇溶剂中加热回流，合成了尚未见报道的５，９，１４，１８，２３，２７，３２，３６－八丁氧基萘酞菁钴（Ⅱ）。并研究了溶剂种类、ＤＢＵ与１，４－二丁氧基２，３－二氰基萘摩尔比、回流时间等因素对配合物产率的影响。对产物进行了元素分析、ＩＲ、ＵＶ－Ｖｉｓ光谱及ＴＧ和ＤＴＧ的测定。5,9,14,18,23,27,32,36-Octabutoxy 2,3-naphthalocyanine cobalt(Ⅱ) was synthesized by refluxing-1,4-dibutocynaphthalene-2,3-dicarbonnitrles with anhydrous cobalt chloride in alcohol solvents in the presence of 1,8-diazabicycio[540]undec-7-ene(DBU) The mehtod has the advantage of simple procedure, mild reaction conditions and high yield In addition, the product was purified easily The effects of solvents, DBU/BNDN(mol ratio) and reflux time on the yield of product were investigated The product was characterized by elemental analysis, IR, UV-Vis The thermol stability of (BuO)_8NPcCo was studied by TG and DTG

关 键 词：八丁氧基 萘酞菁钴 合成 表征 性质 

分 类 号：O614.812[理学—无机化学]