基团贡献法研究甲基丙烯酸酯聚合物特性参数  

STUDY ON PARAMETERS OF POLY(METHACRYLATE) BY THE METHOD OF GROUP CONTRIBUTIONS

作　　者：冯亚凯[1,2] 孙经武[1,2] 黄家贤 李春荣 朱端慧[1,2] 王志军 胡静[1,2] 

机构地区：[1]天津大学应用化学系 [2]南开大学化学系

出　　处：《高分子学报》1998年第3期350-354,共5页Acta Polymerica Sinica

摘　　要：基团贡献法研究甲基丙烯酸酯聚合物特性参数冯亚凯孙经武黄家贤李春荣朱端慧王志军胡静（天津大学应用化学系天津３０００７２）（南开大学化学系天津３０００７１）关键词基团贡献，ＭａｒｋＨｏｕｗｉｎｋ方程，甲基丙烯酸２，２，３，３四氟丙酯，甲基丙烯酸酰基...A series of methacrylate monomers, such as 2,2,3,3-tetrafluoropropyl, acetoxyethyl, propionyloxyethy1,buthyloxyethyl,isobuthyloxyethyl,tertpentanoxythy1 and (2-glycidy1-ether) ethy1 methacrylate, were synthesized. Their homopolymers and copolymers with high molecular weight were obtained by radical polymerization. By measuring with light scattering and viscosity, the MarkHouwink equations of those homopolymers were determined. The group contribution method was used to calculate the values of index of refraction, dn/dc and parameters of MarkHouwink equations of those homopolymers based on cohesive energy, molar volume and molar attraction constant.

关 键 词：PMAIBE PMANBE PMAPE PMATFP PMAAE PMAGEE 性质 

分 类 号：O633.14[理学—高分子化学]