2-硝基-10-羟基-5，10-二氢磷杂吖嗪-10-氧化物的还原研究  

Study on the reduction of compound 2-nitro-10-hy droxy-5,10-dihydrophenophosphazing-10-oxid

作　　者：崔金海[1] 王宫南[1] 尹志刚[2] 占桂荣[1] 

机构地区：[1]开封大学化工学院,河南开封475001 [2]郑州轻工业学院,河南郑州450001

出　　处：《化学研究与应用》2009年第6期891-894,共4页Chemical Research and Application

基　　金：河南省教育厅自然科学项目(200615003);开封市自然科学项目(070135)

摘　　要：2-nitro-10-hydroxy-5,10-dihydrophenophosphazine-10-oxide can be reduced easily with hydrous hydrazine by Fe/MgO catalyst.The reduced compound was detected by IR and HNMR.It showed that the reduction yield is 94%.The catalyst can be used in reduction for three times.This reduction method has a lower cost,less pollution to environment and suit to the industrializing demand for dye intermediate production.2-nitro-10-hydroxy-5,10-dihydrophenophosphazine-10-oxide can be reduced easily with hydrous hydrazine by Fe/MgO catalyst. The reduced compound was detected by IR and HNMR. It showed that the reduction yield is 94%. The catalyst can be used in reduction for three times. This reduction method has a lower cost, less pollution to environment and suit to the industrializing demand for dye intermediate production.

关 键 词：2-硝基10-羟基-5  10-二氢磷杂吖嗪-10-氧化物 铁镁滑石催化剂 水合肼 

分 类 号：TQ031.6[化学工程]