Stereoselective Synthesis and Crystal Structure Analysis of N-Naphthyl-2-deoxy-α-D-ribopyranosylamine  

作　　者：尚培华 成昌梅 杨永冲 王如骥 赵玉芬 

机构地区：[1]Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education),Department of Chemistry, Tsinghua University

出　　处：《Chinese Journal of Structural Chemistry》2009年第6期761-765,共5页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China (No. 20132020)

摘　　要：A new compound N-naphthyl-2-deoxy-α-D-ribopyranosylamine was synthesized and structurally determined. It crystallizes in the orthorhombic system, space group P212121 with a = 8.361（2）, b = 12.432（3）, c = 12.791（4） A^°, Z= 4, V= 1329.6（6） A^°^3, Dc= 1.295 g/cm^3, F（000） = 552, Cl5H17NO3 and Mr= 259.30. All the active hydrogen atoms are involved in the formation of hydrogen bonds in the molecule.A new compound N-naphthyl-2-deoxy-α-D-ribopyranosylamine was synthesized and structurally determined. It crystallizes in the orthorhombic system, space group P212121 with a = 8.361（2）, b = 12.432（3）, c = 12.791（4） A^°, Z= 4, V= 1329.6（6） A^°^3, Dc= 1.295 g/cm^3, F（000） = 552, Cl5H17NO3 and Mr= 259.30. All the active hydrogen atoms are involved in the formation of hydrogen bonds in the molecule.

关 键 词：N-naphthyl-2-deoxy-α-D-ribopyranosylamine synthesis X-ray diffraction crystal structure 

分 类 号：O621.25[理学—有机化学]