对甲酚在碳纳米管修饰电极上的电化学行为及其测定  

Electrochemical Behavior and Determination of P-cresol on Carbon Nanotubes Modified Electrode

作　　者：濮文虹[1] 郑燕琼[1] 杨昌柱[1] 张敬东[2] 崔艳萍[1] 刘宏波[1] 

机构地区：[1]华中科技大学环境科学与工程学院,湖北武汉430074 [2]华中科技大学环境化学与化工系,湖北武汉430074

出　　处：《新技术新工艺》2009年第6期100-103,共4页New Technology & New Process

基　　金：湖北省华中科技大学科研基金资助项目(No.2006Z002A)

摘　　要：研究了对甲酚在多壁碳纳米管修饰玻碳电极(MWNTs/GC)上的电化学行为。MWNTs/GC电极对对甲酚具有良好的电催化作用,相比玻碳电极对甲酚的氧化峰电位负移73 mV,峰电流约为玻碳电极上的4倍。同一电极重复扫描10次后,对甲酚在碳纳米管上的峰电流仍能达到最初电流的86.8%,而GC电极在相同浓度对甲酚中重复扫描3次后,峰电流降到最初电流的37.2%,表明碳纳米管提高了GC电极检测对甲酚的稳定性。研究了溶液pH值和扫描速率对对甲酚氧化的影响。并采用计时电流法研究了峰电流与对甲酚的浓度关系,结果显示峰电流与对甲酚的浓度在2.0×10-7～2.0×10-4mol/L范围内呈良好线性关系,检出限为9.3×10-8mol/L(S/N=3)。In this paper, electrochemical behavior of p-cresol on MWNTs modified glassy carbon electrode （MWNTs/ GC） was studied. The result shows that MWNTs/GC electrode plays a great role on catalyzing the p cresol oxidation. Compared with the glassy carbon electrode, the anodic peak potential of p-cresol shifts negatively for 73 mV,and oxidation peak current reaches 4 times. After scanned one electrode repeatedly for 10 times, the oxidation peak current of p-cresol on MWNTs/GC electrode still retains 86.8% of the original current,while rescan p-cresol at GC electrode for 3 times,the oxidation peak current decreased to 37.2% of the original current, the results show that the MWNTs/GC electrode can improve the stability of GC electrode. Moreover the influences of the pH value and scan rates on the oxidation of p-cresol were also studied and the relationship between current and concentration of p-cresol was studied by chronoamperometry. Finally the results show that the peak current is linearly proportional to the concentration of p-cresol in the range from 2.0 ×10^-7 to 2.0 ×10^-4 mol/L,the detection limit is g. 3×10^-8 mol/L（S/N=3）.

关 键 词：碳纳米管 对甲酚 循环伏安 稳定性 

分 类 号：O657.1[理学—分析化学]