导电高分子与丙烯酸酯的接枝共聚反应研究  

Study on the Graft Copolymerization of Conducting Polymer and Acrylate

作　　者：黄智敏[1] 王玉华[1] 邓安民[1] 

机构地区：[1]南昌航空大学院环化学院,江西南昌330063

出　　处：《广州化工》2009年第3期94-95,103,共3页GuangZhou Chemical Industry

基　　金：江西省自然科学基金资助项目(No.200GZH1495)

摘　　要：通过β-噻吩丙烯酸甲酯的自由基聚合,获得了聚(噻吩丙烯酸甲酯)(P-TAc)。GPC测得其数均分子量为2.4×104。化学氧化(P-TAc)获得聚丙烯酸甲酯-聚噻吩接枝共聚物。用FTIR光谱和Raman光谱确定了结构。材料的电导率为0.15 S.cm-1。Poly（3-thienyl）methylacrylate （P-tAc） was synthesized by radical polymerization of 3-thienyl methylacrylate. The average molecular weight was measured to be 2.4 × 10^4. Graft copolymer of poly（methylacrylate）-polythiophene was obtained by chemical oxidation of PE. The structures of the polymers were characterized by FTIR and Raman spectra. The conductivity of the material was 0.15 S·cm^-1.

关 键 词：聚噻吩 接枝共聚 聚噻吩丙烯酸甲酯 丙烯酸酯 

分 类 号：TQ325.7[化学工程—合成树脂塑料工业] O631.23[理学—高分子化学]