薄层色谱法分离四苯基卟啉和四苯基钴卟啉  

Separation of Tetraphenyl Porphine and Tetraphenyl Cobaltoporphine by Thin Layer Chromatography

作　　者：贾长英[1] 唐丽华[1] 李卫华 张晓娟[1] 张丹阳[1] 李季[1] 

机构地区：[1]沈阳工业大学石油化工学院,辽阳111003 [2]辽阳石油化纤公司金兴化工厂,辽阳111003

出　　处：《理化检验（化学分册）》2009年第6期664-665,668,共3页Physical Testing and Chemical Analysis(Part B:Chemical Analysis)

基　　金：辽宁省教育厅A类项目,环己烷一步氧化法合成己二酸用催化剂的研究(05L289)

摘　　要：提出了用薄层色谱分离四苯基卟啉和四苯基钴卟啉的方法。方法中以石油醚-二甲苯(体积比为2∶1)二元溶剂体系为展开剂,在硅胶薄层板上分离了四苯基卟啉和四苯基钴卟啉,所得斑点清晰、无拖尾。应用此薄层色谱法跟踪检测了四苯基钴卟啉的合成。Tetraphenyl porphine and tetraphenyl cobaltoporphine were separated by thin layer chromatography. The plate adsorbed with a thin layer of silica gel was used as the stationary phase, and a mixture of petroleum ether and xylol （mixed in the ratio of 2 to 1 ） was used as the mobile phase （also as developing solvent）. The spots of the 2 compounds were separated clearly and without tailing. The proposed method was used as tracing detection in the preparation of TPP-Co.

关 键 词：薄层色谱 四苯基卟啉 四苯基钴卟啉 

分 类 号：O658[理学—分析化学]