基于药物分子组装的含有Keggin型金属氧簇的超分子化合物的晶体结构和电化学性质研究  

Crystal structure and electrochemistry of a supramolecular assembly based on organic medical molecule and Keggin polyoxometalate

作　　者：徐丽芳[1] 

机构地区：[1]辽宁农业职业技术学院,辽宁营口115009

出　　处：《分子科学学报》2009年第3期205-208,共4页Journal of Molecular Science

摘　　要：通过水热方法合成了超分子化合物(Hfcz)3(PMo12O40).3H2O.单晶X射线衍射分析表明化合物结晶于三方晶系,P-3c空间群.化合物中的两种亚单元通过氢键作用形成了3D超分子结构.化合物堆积形成了孔道结构.此外,循环伏安法研究结果表明了化合物展示三个连续的双电子还原过程.The supramolecular compound of （Hfcz）3 （PMo12O40）·3H2O has been isolated by hydrothermal method. X-ray single crystal diffraction analysis reveals that the compound crystallizes in trigonal and space group of P-3c. There are two kinds of subunits in the unique unit which are linked each other through hydrogen bonds to generate a 3D supramolecular structure with porous features. In addition, the electrochemical property of the compound has been researched using cyclic voltammograms, which shows three consecutive two-electron processes.

关 键 词：多金属氧酸盐 有机药物分子 超分子 

分 类 号：O612[理学—无机化学]