2-二苯基膦基氨基吡啶合钯的结构及其催化活性  

STRUCTURE AND CATALYTIC ACTIVITY OF Pd(Ⅱ) COMPLEXES CONTAINING 2-(DIPHENYLPHOSPHINOAMINO) PYRIDINE(PAP)

作　　者：黄唯平[1] 张新杰[1] 吴世华[1] 张书笈[1] 赵维君[1] 

机构地区：[1]南开大学化学系,天津300071

出　　处：《南开大学学报（自然科学版）》1998年第2期93-95,共3页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：国家自然科学基金

摘　　要：合成了二个含2-二苯基膦基氨基吡啶的Pd（Ⅱ）配合物，并进行了元素、红外分析，评价了它们在乙醇羰基化反应中的催化活性．单晶结构测试结果表明，Pd（PAP）Cl2的中心离子和配位原子几乎处于同一平面．篢wo Pd(Ⅱ) complexes containing 2-(diphenylphosphinoamino) pyridine(PAP) were synthesized. Elementary analysis and IR spectrum were used to characterized them. The catalytic activity of them for carboxylation of ethanol was also tested. The X-ray crystallography of Pd (PAP) Cl2 shows that its center ion Pd (Ⅱ) and other donor atoms are almost in the same plane.

关 键 词：吡啶 乙醇羰化 PAP 钯配合物 催化活性 

分 类 号：O614.823[理学—无机化学] O643.361[理学—化学]