水溶性C_(60)赖氨酸衍生物及其铜配合物的合成与表征  

SYNTHESIS AND CHARACTERIZATION OF LYSINE C_(60) ADDUCT AND ITS Cu(Ⅱ) COMPLEXES

作　　者：陈中方[1] 潘荫明[1] 马克勤[1] 郭蔚辉 郝策[1] 赵学庄[1] 唐敖庆[2] 

机构地区：[1]南开大学化学系,天津300071 [2]吉林大学理论化学研究所,长春130023

出　　处：《南开大学学报（自然科学版）》1998年第2期89-92,共4页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：国家自然科学基金

摘　　要：合成了水溶性C60赖氨酸衍生物及其铜配合物，通过元素分析、UV、IR、1HNMR、13CNMR对产物进行了表征．Lysine sodium salt reacted with C60 to give a water-soluble derivative Ⅰ, which has the characteristic parent unit of α-aminoacid. Acidification of Ⅰ yields a less soluble derivative Ⅱ. Since compound Ⅱ has bidonor ligand, it may complexe with many metals,treated with Cu(ClO4)2, insoluble Cu(Ⅱ) commplexes Ⅲ were obtained. FTIR, UV-Vis,elemental analysis, 1HNMR and 13CNMR spectrum have been used to characterize these new compounds. The paramagnetic propertity of the new Cu(Ⅱ) complexes Ⅲ has been studied by ESR spectrum.

关 键 词：赖氨酸加成物 ESR谱 碳60 铜配合物 

分 类 号：O623.736[理学—有机化学] O614.121[理学—化学]