Decoration of C_(60) nanorods with nickel and their magnetic properties  

作　　者：CHEN Ao LIU BingBing HOU YuanYuan WEN GeHui LIU DeDi LU ShuangChen LI ZePeng LI XiangLin ZOU YongGang ZOU Bo LI DongMei CUI Tian ZOU GuangTian 

机构地区：[1]State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

出　　处：《Chinese Science Bulletin》2009年第14期2539-2542,共4页

基　　金：Supported by the National Natural Science Foundation of China (Grant Nos. 10674053, 20773043, 10574053);Program for Changjiang Scholar and Innovative Research Team in University (Grant No. IRT0625);National Basic Research Pro-gram of China (Grant Nos. 2005CB724400, 2001CB711201);Project for Scientific and Technical Developments of Jilin Province, 2007 Cheung Kong Scholars Programme of China;National Fund for Fostering Talents of Basic Science (Grant No. J0730311)

摘　　要：We studied the coating of C60 nanorods with nickel by electroless plating method and investigated their magnetic properties. The morphology and structure of the nickel layer coated on C60 nanorods were characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and Raman spectroscopy. The coated nickel is in the form of nano-sized crystals and becomes a continuous layer as reaction time increases. The hysteresis loop shows a super paramagnetic characteristic similar to that of nanometer-sized nickel particle. These results suggest that the average size of nickel particles on C60 rods is below 10 nm. Our study has shown that electroless plating is an efficient and simple method for coating C60 nanorods with nickel.We studied the coating of C60 nanorods with nickel by electroless plating method and investigated their magnetic properties. The morphology and structure of the nickel layer coated on C60 nanorods were characterized by transmission electron microscopy （TEM）, energy-dispersive X-ray spectroscopy （EDX）, X-ray diffraction （XRD） and Raman spectroscopy. The coated nickel is in the form of nano-sized crystals and becomes a continuous layer as reaction time increases. The hysteresis loop shows a super paramagnetic characteristic similar to that of nanometer-sized nickel particle. These results suggest that the average size of nickel particles on C60 rods is below 10 nm. Our study has shown that electroless plating is an efficient and simple method for coating C60 nanorods with nickel.

关 键 词：纳米镍粒子 C60 磁学性质 透射电子显微镜 纳米涂层 装饰 化学镀镍 X射线光谱 

分 类 号：O613.71[理学—无机化学] TG174.453[理学—化学]