铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展  

Progress of Rhodium/Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins

作　　者：刘雯静[1] 袁茂林[1] 付海燕[1] 李瑞祥[1] 陈华[1] 

机构地区：[1]四川大学化学学院有机金属络合催化研究所、绿色化学与技术教育部重点实验室,四川成都610064

出　　处：《催化学报》2009年第6期577-586,共10页

基　　金：国家自然科学基金(29792074)

摘　　要：烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.Hydroformylation of olefins is one of the important industrial processes. Due to the strong coordination ability and the good catalytic activity of their rhodium complexes, diphosphine ligands can increase the selectivity for linear aldehydes in the hydroformylation of internal olefins. The influence of structural changing of diphosphine ligands on the activity and the selectivity for linear aldehydes in hydroformylation of internal olefins were also extensively introduced. This review systematically summarized the progress made in homogeneous hydroformylation of internal olefins catalyzed by dipbosphine-rhodium complexes in the past few years.

关 键 词：铑 双膦配体 内烯烃 氢甲酰化 

分 类 号：O643.32[理学—物理化学]