四苯基卟啉衍生物的合成、表征及光物理和电化学性质  

Synthesis,Characterization,Photophysical and Electrochemical Properties of Tetraphenylporphyrin Derivatives

作　　者：陈连清[1] 渠星宇[1] 李群丽[1] 施超[1] 

机构地区：[1]中南民族大学化学与材料科学学院催化材料科学湖北省暨国家民委-教育部共建重点实验室,武汉430074

出　　处：《中南民族大学学报（自然科学版）》2009年第2期18-22,共5页Journal of South-Central University for Nationalities：Natural Science Edition

基　　金：国家自然科学基金资助项目(20702064);中南民族大学自然科学基金资助项目(YZZ07007)

摘　　要：为寻求更高效的发光材料,通过改进的Alder法合成了四苯基卟啉、含吸电子基团的四(对硝基苯基)卟啉和含推电子基团的四(对甲氧基苯基)卟啉,对这些化合物进行了红外、质谱、元素分析等表征,并测试了其紫外、荧光与电化学性质,探讨了取代基对卟啉化合物光物理性能及电化学性质的影响.To find highly efficient luminescent materials, three tetraphenyllporphyrin derivatives, including electronic withdrawing substituent （-NO2） and electronic donating substitute （-OCH3） were synthesized by improved methods of Alder. Their structures have been fully characterized by FT-IR, MS and elemental analysis. The electronic absorption and fluorescence and eletrochemical properties of these compounds have been systematically investigated. The relationships between their photophysical properties and structures have been discussed.

关 键 词：四苯基卟啉衍生物 荧光性能 电化学性质 

分 类 号：TB383[一般工业技术—材料科学与工程]