固体酸SO_4^(2-)/ZrO_2-Al_2O_3催化合成乙腈的研究  

Synthesis of Acetonitrile Catalysted by Solid Acid SO_4^(2-)/ZrO_2-Al_2O_3

作　　者：侯雪梅[1] 闫丽[1] 张鑫[1] 李艳伟[1] 李传碧[1] 

机构地区：[1]吉林师范大学化学学院,吉林四平136000

出　　处：《吉林师范大学学报（自然科学版）》2009年第2期108-109,共2页Journal of Jilin Normal University:Natural Science Edition

基　　金：吉林省科技发展计划项目(20080406)

摘　　要：合成了由乙酸与氨气合成乙腈的催化剂固体酸SO42-/ZrO2-Al2O3,该催化剂具有催化效率高、选择性好、对环境无污染等特点,使乙腈产品产率由30%提高到85%,纯度提高到99.1%.In this paper, we synthesize directly acetonitrile through gasified acetic acid and ammonia, with a catalytic efficiency, easy separation, reusable, non-polluting to the environment, new high-performance SO4^2-/ZrO2-Al2O3 catalysts. Consequently, the yield of acetonitrile is from 30% to 85%, the purity reach to 99.1%, the technology also improve overall economic efficiency.

关 键 词：SO42-/ZrO2-Al2O3 催化 乙腈 固体酸 纯度 

分 类 号：O621.3[理学—有机化学]