蒽环类叔胺的合成与表征  

Synthesis and Characterization of Tertiary Amine with Anthracene Ring

作　　者：刘文杰[1] 陈志钊[1] 曹德榕[1] 

机构地区：[1]华南理工大学化学与化工学院,广州510640

出　　处：《河南科学》2009年第7期793-795,共3页Henan Science

基　　金：国家自然科学基金(20872038);高等学校博士学科点专项科研基金(20060561024)资助项目

摘　　要：以9-蒽甲醛为原料,和苄胺、芳香胺在冰乙酸的催化下脱水生成席夫碱,经过硼氢化钠还原,和3,5-二烷氧基苄基氯发生亲核取代反应,合成了一系列蒽环类叔胺化合物,并通过NMR、质谱对其结构进行了表征.A series of novel tertiary amine with anthracene ring were synthesized from 9-anthraldehyde with ben- zylamine or aromatic amines as the starting material via the schiff base catylized by AcOH, then reduced by NaBH4, followed by nucleophilic substitution reaction with 3,5-dialkoxybenzyl chloride. The structure of new compounds was determined by NMR and MS.

关 键 词：9-蒽甲醛 蒽环 叔胺 合成 

分 类 号：O626.2[理学—有机化学]