可作为聚合单体的含硫杂杯[4]芳烃的合成  

Synthesis of Thiacalixarene Used as Polymer Monomer

作　　者：刘小毛[1] 咸春颖[1] 朱旭栋[1] 郑利民[1] 

机构地区：[1]东华大学化学化工与生物工程学院,上海201600

出　　处：《应用化学》2009年第7期848-850,共3页Chinese Journal of Applied Chemistry

摘　　要：以对叔丁基苯酚为起始原料,经逐步反应在杯芳烃母体下缘引入含硫类冠醚结构,上缘引入2个氨基,得到可作为聚合单体的二氨基含硫杯芳烃[4]衍生物,并通过1HNMR、MS、IR、元素分析和熔点测试技术确定了产物结构。The thiacalixarene was synthesized from p-tert-butycalix [ 4 ] arene, following a series of reactions by decorating thiacrown ethers on the bottom edge and two aminos on the top edges. The target product could be used as the polymer monomer and the structure was characterized by ^1H NMR, MS, IR, elemental analysis and meahing point measurement.

关 键 词：杯芳烃 含硫 氨基 硫冠醚 

分 类 号：O621.3[理学—有机化学]