新型有机-无机杂化吡啶盐化合物的设计合成  

Design and syntheses of novel organic-inorganic hybrid pyridinium compounds

作　　者：李胜利[1] 杨捷[1] 郁建华[1] 吴杰颖[1] 田玉鹏[1] 

机构地区：[1]安徽大学化学化工学院,安徽合肥230039

出　　处：《安徽大学学报（自然科学版）》2009年第4期66-70,共5页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(50532030);安徽省高等学校教学研究项目(01010175)

摘　　要：设计合成3种非线性光学效应的新型有机-无机杂化物,即3种不对称D-π-A型取代苯乙烯基吡啶盐化合物,并运用常规方法进行表征.以实验证实,从分子设计,通过分子组装,是合成有机-无机杂化型化合物的有效方法,同时培养出其中一种化合物的高质量单晶,解析了晶体结构,分析和探讨了化合物的组成-结构-性质之间的关系.The materials of pyridinium compounds with striking optical nonlinearities were briefly discussed in the thesis. The research aim was mainly focused on the design and syntheses of organic-inorganic hybrid complexes. Three organic-inorganic hybrid coordination compounds, which contained the ambidentate thiocyanate （SCN^-） ligand, metal ion and pyridinium deriver, had been synthesized by self-assembly, respectively. They were characterized by modern analysis methods such as IR, UV, Fluorescent spectra, Element analysis and TGA, etc. The results were given and discussed, and some significant conclusions had been got.

关 键 词：有机-无机杂化 吡啶盐 合成 结构 

分 类 号：O635[理学—高分子化学]