苯磺酸-3-硝基对甲苯酯的合成及晶体结构  

Synthesis and crystal structure of phenyl 4-methyl-3-nitro-benzenesulfonate

作　　者：谷利军[1] 杨秉勤[1] 李敏[1] 高波[1] 陆振欢[1] 

机构地区：[1]西北大学化学系,陕西西安710069

出　　处：《化学试剂》2009年第7期493-494,497,共3页Chemical Reagents

基　　金：国家自然科学基金资助项目(20572085)

摘　　要：以对甲苯酚为原料,超声波辅助下高收率得到苯磺酸对甲苯酯,经硝化合成了标题化合物,用IR、1HNMR、元素分析对其进行表征,X-射线分析数据表明苯磺酸-3-硝基对甲苯酯属于单斜晶系,P2(1)/n空间群。Phenyl 4-methyl-benzenesulfonate was synthesized from 4-methyl-phenol with high yield under supersonic irradiation. Furthermore, phenyl 4-methyl-3-nitro-benzenesulfonate was synthesized via nitration of 4-methyl-benzenesulfonate and was characterized by IR,tHNMR,and elemental analysis. The crystal structure of phenyl 4-methyl-3-nitro-benzenesulfonate was monoclinic, with a space group of P2（1）/n.

关 键 词：苯磺酸-3-硝基对甲苯酯 合成 晶体结构 

分 类 号：O626.75[理学—有机化学]