端羟基聚丁二烯的环氧化改性研究进展  

Research Progress in Epoxidation Modification of Hydroxyl-Terminated Polybutadiene

作　　者：张进[1] 王勃[1] 韩珺[1] 曹光宇[1] 

机构地区：[1]黎明化工研究院,河南洛阳471000

出　　处：《化学推进剂与高分子材料》2009年第4期17-20,共4页Chemical Propellants & Polymeric Materials

摘　　要：详细介绍了端羟基聚丁二烯环氧化改性的新方法。比较了过氧甲酸原位法、过氧乙酸原位法、单过氧邻苯二甲酸原位法等几种方法的优缺点。相对于其他过氧酸原位法,过氧甲酸原位法具有工艺简单、自催化和成本低等优点,但开环几率较高,通过优化并严格控制反应条件后可得到有效改善。New methods for epoxidation modification of hydroxyl-terminated polybutadiene are reviewed in detail. The advantages and disadvantages of the performic acid in-situ method, peracetic acid in-situ method, monoperphthalic acid in-situ method, etc. are compared. Compared to other peracid in-situ method, performic acid in-situ method possesses the advantages of simple process, selfcatalysis and low cost, but higher ring-opening probability. The disadvantage can be improved by optimizing and strictly controlling reaction conditions.

关 键 词：HTPB改性 EHTPB 环氧化 过氧酸 原位 

分 类 号：TQ316.34[化学工程—高聚物工业]